homogeneouscatalysis相关论文
Direct functionalization of inert C(sp3)-H bonds is a topic of immense contemporary interest and exceptional value in or......
Au(Ⅰ)-Catalyzed 6-endo-dig Cyclizations of Aromatic 1,5-Enynes to 2-(Naphthalen-2-yl)anilines Leadin
A gold(Ⅰ)-catalyzed 6-endo-dig cyclization of aromatic 1,5-enynes was developed to synthesize 2-(naphthalen-2-yl)anilin......
Theoretical Study of Non-heme Mn(Ⅴ)-oxo Complexes:Formation Mechanism,Electronic Nature,and Hydroxyl
Many non-heme manganese complexes exhibit high reactivity and enantioselectivity for the activation of C-H bonds.Recentl......
Horizontally and Vertically Concerted Steric Strategy in α-Diimine Nickel Promoted Ethylene (Co)Poly
Steric bulk plays a significantly paramount role in late transition metal promoted olefin (co)polymerization in terms of......
Kinetics and mechanistic investigation of epoxide/CO2 cycloaddition by a synergistic catalytic effec
Formation of styrene carbonate (SC) by the cycloaddition of CO2 to styrene oxide (SO) catalysed by pyrrolidinopyridinium......
Design of Phosphorus Ligands with Deep Chiral Pockets: Practical Synthesis of Chiral β-Arylamines by
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Facile One-Pot Palladium-Catalyzed Sequential Coupling to Diarylmethanes by Using Aryl Methyl Ketone
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The noble transition-metal(i.e.,Pd,Ru,Rh,and Ir)catalysts play a dominant role in the stage of inert C-H bond functional......
The effects of substituents,axial ligands,and rates of electrons transfer for cobalt corrole complex
Three cobalt complexes of 5,10,15-tris(pentafluorophenyl)corrole(1)and 5,15-bis-(pentafluorophen yl)-10-(4)-(1-pyrenyl)p......
Air-stable Ru(Ⅱ)-NNN Pincer Complexes for Efficient Coupling of Aromatic Diamines and Alcohols to 1H
Two new phosphine-free Ru(Ⅱ)-NNN pincer complexes([RuCl(L1)(CH3CN)2]Cl(1)and [RuCl(L2)(CH3CN)2]Cl(2),L1 = 2,6-bis(1H-im......
Synthesis of a Mixed Silylene-Carbene Chelate Ligand from an N-Heterocyclic Silylcarbene Mediated by
N-heterocyclic carbenes(NHCs)represent one of the most widely utilized supporting ligands in transition metal(TM)chemist......
Main observation and conclusionrnWe report herein a Re-based tricarbonyl catalyst [fac-Re(L1)(CO)3Cl] (Re1) bearing a sp......
Main observation and conclusionrn[Cp*Co(CO)l2] effectively catalyzes pyridyl-directed C-H allylation of arenes with ally......
Synthesis of Cyclic Polyolefin:Ring-Opening Metathesis Polymerization by Binuclear Vanadium Complexe
Main observation and conclusionrnRing-opening metathesis polymerization (ROMP) of norbornene by binuclear vanadium alkyl......
Aromaticπ-πInteraction as A Control Element in Asymmetric Catalysis with Ar-BINMOLs and Its Derivati
The importance of aromatic interactions(π-πstacking,CH-π,cation-π and anion-π interactions) in supramolecular chemi......
The introduction of N-heterocyclic carbenes(NHCs)as ligands for transition metals has generated many breakthroughs i......
Non-Noble Metals for Noble Tasks-Efficient Homogeneous Hydrogenations and Hydrosilylations with Midd
Replacing noble metals in homogeneous catalysis is a great and timely challenge for academic and industrial research.How......
Computational chemistry has played an important role in elucidating mechanisms of metal-mediated organic and enzymat......
Since the pioneering work on Cr(Ⅲ)-catalyzed enantioselective[4+2]/allylboration reported by Hall and co-workers,a vari......
This review covers H-H bond cleavage of dihydrogen(H2)mediated by structurally well-defined rareearth metal(scandium,ytt......
庚烯羰化制醇的原位红外光谱表征１）焦凤英胡庆云陈艳晶（济南大学实验中心济南２５０００２）牛建中殷元骐（中国科学院兰州化学物理研究所羰基合成与选......
介绍了仿生氧载体研究的意义、生物体内氧载体类型、三类仿生氧载体的特点及均相催化氧化性能的研究现状。......
